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Über die Darstellung von Trilithium-trisulfimid (Trilithium-1,3,5,2,4,6-trithiatriazin-1,1,3,3,5,5-hexaoxid) und die thermische Zersetzung einiger Salze des Trisulfimids

Authors :
Nachbaur, E.
Baumgartner, E.
Source :
Monatshefte für Chemie / Chemical Monthly; July 1973, Vol. 104 Issue: 4 p1131-1138, 8p
Publication Year :
1973

Abstract

Trilithiumhexaoxocyclotrithiazane<superscript>*</superscript> (trilithiumtrisulfimid) has been prepared for the first time by reaction of triammoniumtrisulfimid with LiOH in a solid state reaction and by using high boiling alcohols as reaction medium. The thermolysis of different salts of trisulfimid (Na-, K-, Li-, Ag-, NH<subscript>4</subscript>-salt) has been studied by thermoanalytical methods in the region between 25–500 dC. The course of decomposition of these compounds is discussed by IR and chromatographic measurements.

Details

Language :
English
ISSN :
00269247 and 14344475
Volume :
104
Issue :
4
Database :
Supplemental Index
Journal :
Monatshefte für Chemie / Chemical Monthly
Publication Type :
Periodical
Accession number :
ejs16239244
Full Text :
https://doi.org/10.1007/BF00903932