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Complexes of osmium (III) obtained from OsO4 and ethylenethioureas. A kinetic study of the reduction in HClO4 solutions
- Source :
- Transition Metal Chemistry; April 1982, Vol. 7 Issue: 2 p69-71, 3p
- Publication Year :
- 1982
-
Abstract
- OsO<subscript>4</subscript> reacts with imidazolidine-2-thione and itsN-methyl andN-ethyl derivatives in acidified 1:1 vol. H<subscript>2</subscript>O:EtOH to give [OsL<subscript>6</subscript>]<superscript>3+</superscript>. Complexes obtained in the presence of HClO<subscript>4</subscript> or HBF<subscript>4</subscript> have been isolated as crystals and characterized by elemental analysis, i.r. spectroscopy and magnetic measurements.
Details
- Language :
- English
- ISSN :
- 03404285 and 1572901X
- Volume :
- 7
- Issue :
- 2
- Database :
- Supplemental Index
- Journal :
- Transition Metal Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs15351897
- Full Text :
- https://doi.org/10.1007/BF00618184