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Chirality Transfer from Epoxide to Carbanion: Base-Induced Alkylation of O-Carbamoyl Cyanohydrins of β-Silyl-α,β-epoxy Aldehyde
- Source :
- European Journal of Organic Chemistry; June 2008, Vol. 2008 Issue: 18 p3061-3064, 4p
- Publication Year :
- 2008
-
Abstract
- Enantioselective C–C bond formation at an α-position of a nitrile group with an external electrophile can be realized, although in modest ee, with the aid of both the concerted process of an epoxysilane rearrangement and a carbamoyl group. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Details
- Language :
- English
- ISSN :
- 1434193X and 10990690
- Volume :
- 2008
- Issue :
- 18
- Database :
- Supplemental Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs14440622
- Full Text :
- https://doi.org/10.1002/ejoc.200800300