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The spectra and analysis of the v2 and v5 infrared bands of 12CD3F
- Source :
- Molecular Physics; June 1982, Vol. 46 Issue: 2 p223-237, 15p
- Publication Year :
- 1982
-
Abstract
- The infrared spectrum of 12CD3F from 1040 to 1200 cm-1 has been analysed using a new program which diagonalizes the complete interaction hamiltonian matrix for the v2 and v5 ro-vibrational levels. The program fits simultaneously the microwave, laser Stark and diode spectra and over 800 transitions in the Nicolet FTIR spectrum. A comparison of the calculated and observed infrared spectra shows the phases of the dipole moment derivatives to be of opposite sign. Several new Stark spectra have been assigned.
Details
- Language :
- English
- ISSN :
- 00268976 and 13623028
- Volume :
- 46
- Issue :
- 2
- Database :
- Supplemental Index
- Journal :
- Molecular Physics
- Publication Type :
- Periodical
- Accession number :
- ejs12838794
- Full Text :
- https://doi.org/10.1080/00268978200101221