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An Expedient Method for Resolution of 3-Amino-3-(3‘-pyridyl)propionic Acid and Related Compounds

Authors :
Boesch, H.
Cesco-Cancian, S.
Hecker, L. R.
Hoekstra, W. J.
Justus, M.
Maryanoff, C. A.
Scott, L.
Shah, R. D.
Solms, G.
Sorgi, K. L.
Stefanick, S. M.
Thurnheer, U.
Villani, F. J., Jr.
Walker, D. G.
Source :
Organic Process Research & Development; January 2001, Vol. 5 Issue: 1 p23-27, 5p
Publication Year :
2001

Abstract

Preparation of methyl (S)-3-amino-3-(3‘-pyridyl)propionate dihydrochloride in high enantiomeric purity by selective crystallization of a diastereomeric salt of a carboxylic acid precursor (N-BOC-protected) with (1R,2S)-(−)-ephedrine is described. Further demonstration of the usefulness of this procedure to resolve other 3-amino-3-[(substituted)pyridyl]propionic acids is also described.

Details

Language :
English
ISSN :
10836160 and 1520586X
Volume :
5
Issue :
1
Database :
Supplemental Index
Journal :
Organic Process Research & Development
Publication Type :
Periodical
Accession number :
ejs1156347