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Syntheses and X-ray Structures of (2,2-Biphosphinine)-(η<SUP>5</SUP>-pentamethylcyclopentadienyl)ruthenium(I) Dimer and Ruthenium(0) Complexes
- Source :
- Organometallics; November 2000, Vol. 19 Issue: 24 p5247-5250, 4p
- Publication Year :
- 2000
-
Abstract
- Reduction of the [Ru(Cp*)(tmbp)Cl] complex (tmbp = 4,4,5,5-tetramethyl-2,2-biphosphinine) with 1 and 2 equiv of sodium naphthalenide respectively yield a dimeric [Ru(Cp*)(tmbp)]<INF>2</INF> complex and a [Ru(Cp*)(tmbp)][Na(DME)<INF>2</INF>] complex which were both structurally characterized. Trapping the Ru(0) complex with MeI, Ph<INF>3</INF>SnCl, Me<INF>3</INF>SnCl, or H<SUP>+</SUP> affords the corresponding Ru(II) derivatives.
Details
- Language :
- English
- ISSN :
- 02767333 and 15206041
- Volume :
- 19
- Issue :
- 24
- Database :
- Supplemental Index
- Journal :
- Organometallics
- Publication Type :
- Periodical
- Accession number :
- ejs1155161