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Photochemistry of Transition Metal Germylenes and Metallacycles
- Source :
- Organometallics; March 2000, Vol. 19 Issue: 6 p1186-1189, 4p
- Publication Year :
- 2000
-
Abstract
- Group 10 metal germylene complexes of general formula (R<INF>3</INF>P)<INF>2</INF>MGeQ<INF>2</INF> are found to be highly photosensitive. Ambient fluoresent lighting causes complete decomposition of nickel germylene species in less than one minute in the presence of germylene traps. The formation of metallacycle (Et<INF>3</INF>P)<INF>2</INF>Pt(μ-η<SUP>2</SUP>-H<INF>2</INF>CO)Ge[N(SiMe<INF>3</INF>)<INF>2</INF>]<INF>2</INF> and the photochemical cycloreversion reaction are also reported.
Details
- Language :
- English
- ISSN :
- 02767333 and 15206041
- Volume :
- 19
- Issue :
- 6
- Database :
- Supplemental Index
- Journal :
- Organometallics
- Publication Type :
- Periodical
- Accession number :
- ejs1154597