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Boratabenzene Analogues of the Constrained Geometry Polymerization Catalysts

Authors :
Ashe, A. J., III
Fang, X.
Kampf, J. W.
Source :
Organometallics; April 12, 1999, Vol. 18 Issue: 8 p1363-1365, 3p
Publication Year :
1999

Abstract

(4-Dimethylsilyl-tert-butylamido)-N,N-diisopropyl-1-aminoboratabenzene ZrCl<INF>2</INF> (<BO>7a</BO>) and TiCl<INF>2</INF> (<BO>7b</BO>) complexes have been prepared. When activated by excess methylaluminoxane, <BO>7a</BO> and <BO>7b</BO> are catalysts for the polymerization of ethylene.

Details

Language :
English
ISSN :
02767333 and 15206041
Volume :
18
Issue :
8
Database :
Supplemental Index
Journal :
Organometallics
Publication Type :
Periodical
Accession number :
ejs1153810