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NMR Evidence for the Unprecedented Binding of a Naphthalene Group to Copper(I) in Solution
- Source :
- Organometallics; July 20, 1998, Vol. 17 Issue: 15 p3146-3148, 3p
- Publication Year :
- 1998
-
Abstract
- Variable-temperature one- and two-dimensional NMR experiments with [<BO>L</BO>Cu](PF<INF>6</INF>) (<BO>L</BO> = N-(2-(1-naphthyl)ethyl)-1-aza-4,8-dithiacyclodecane) reveal solution binding of the pendant naphthalene group, consistent with the η<SUP>2</SUP> binding found in the solid-state structure. The free energy for the barrier to the process that involves coordination/decoordination of the naphthalene group was estimated to be 12−13 kcal/mol.
Details
- Language :
- English
- ISSN :
- 02767333 and 15206041
- Volume :
- 17
- Issue :
- 15
- Database :
- Supplemental Index
- Journal :
- Organometallics
- Publication Type :
- Periodical
- Accession number :
- ejs1153230