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Synthesis and Characterization of a Novel Diarylgermylene Containing Electron-Withdrawing Groups

Authors :
Bender, J. E., IV
Holl, M. M. Banaszak
Kampf, J. W.
Source :
Organometallics; June 10, 1997, Vol. 16 Issue: 12 p2743-2745, 3p
Publication Year :
1997

Abstract

The fluoroarylgermylene bis[2,4,6-tris(trifluoromethyl)phenyl]germanium(II) was synthesized by the reaction of 2 equiv of [2,4,6-tris(trifluoromethyl)phenyl]lithium with GeCl<INF>2</INF>·dioxane. This monomeric germylene has good thermal stability, despite having the least sterically encumbering set of stabilizing ligands of any alkyl germylene isolated to date.

Details

Language :
English
ISSN :
02767333 and 15206041
Volume :
16
Issue :
12
Database :
Supplemental Index
Journal :
Organometallics
Publication Type :
Periodical
Accession number :
ejs1152197