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Ultrafast Excited-State Proton Transfer from Cyano-Substituted 2-Naphthols
- Source :
- The Journal of Physical Chemistry - Part A; June 19, 1997, Vol. 101 Issue: 25 p4602-4605, 4p
- Publication Year :
- 1997
-
Abstract
- The rate of excited-state proton transfer from four cyano-substituted 2-naphthols was measured in H<INF>2</INF>O and D<INF>2</INF>O by picosecond time-resolved fluorescence. The excited-state acidity constant, pK<INF>a</INF>*, was calculated and compared with previous results and was found to be substitution-dependent, as predicted by the charge-transfer theory. The isotope effect was evaluated for all the compounds of the series. As reported for many other hydroxyaromatic compounds, this effect was more important for the dissociation rate constant than for the recombination rate constant.
Details
- Language :
- English
- ISSN :
- 10895639 and 15205215
- Volume :
- 101
- Issue :
- 25
- Database :
- Supplemental Index
- Journal :
- The Journal of Physical Chemistry - Part A
- Publication Type :
- Periodical
- Accession number :
- ejs1121749