Back to Search
Start Over
Synthesis of a Heterobimetallic Rhodium-Iron Complex Containing an 3-Interaction between Rhodium and the B-Cipso-CorthoUnit of a Triarylborane
- Source :
- Organometallics; December 2006, Vol. 25 Issue: 25 p5835-5838, 4p
- Publication Year :
- 2006
-
Abstract
- Reaction of RhCl(CO)22 with a phosphine/thioether/borane ligand (TXPB) gave Rh(-Cl)(CO)(TXPB) (1), a rare example of a complex containing a M-Cl-BR3bridging interaction. Reaction of 1with KCpFe(CO)2 gave (TXPB)Rh(-CO)2Fe(CO)Cp (2), which contains an unprecedented 3-interaction between rhodium and the B-Cipso-Corthounit of a triarylborane. DFT calculations suggest a bonding description intermediate between that expected for an isolated borane/alkene complex and a fully delocalized allyl-like complex.
Details
- Language :
- English
- ISSN :
- 02767333 and 15206041
- Volume :
- 25
- Issue :
- 25
- Database :
- Supplemental Index
- Journal :
- Organometallics
- Publication Type :
- Periodical
- Accession number :
- ejs10599362
- Full Text :
- https://doi.org/10.1021/om060903m