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The intramolecular cation–π interaction of some aryl amines and its drastic influence on the basicity of them: AIM and NBO analysis.
- Source :
- Computational & Theoretical Chemistry; May2014, Vol. 1036, p51-60, 10p
- Publication Year :
- 2014
-
Abstract
- Highlights: [•] Increasing methylene groups in aryl amines results in higher cation–π interactions. [•] There is good correlation between proton affinities and Hammett’s parameters. [•] Hydrogen atom of ammonium group is responsible for making cation–π interactions. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 2210271X
- Volume :
- 1036
- Database :
- Supplemental Index
- Journal :
- Computational & Theoretical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 95632123
- Full Text :
- https://doi.org/10.1016/j.comptc.2014.02.008