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Palladium-catalyzed Decarboxylative [4+1] Cyclization of γ-Methylidene-δ valerolactones with Isocyanides.

Authors :
Soyoung Park
Ryo Shintani
Hayashi, Tamio
Source :
Chemistry Letters; 3/5/2009, Vol. 38 Issue 3, p50-50, 1p
Publication Year :
2009

Abstract

A palladium-catalyzed decarboxylative cyclization of γ-methylidene-δ-valerolactones with isocyanides has been developed to afford conjugated cyclopentenimines under mild conditions. Some preliminary results toward the development of an asymmetric variant have also been described. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
38
Issue :
3
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
36886545
Full Text :
https://doi.org/10.1246/cl.2009.204