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XANES in condensed systems.

Authors :
Mandelkow, Eckhard
Dewar, Michael J. S.
Dunitz, Jack D.
Hafner, Klaus
Heilbronner, Edgar
Itô, Shô
Lehn, Jean-Marie
Niedenzu, Kurt
Raymond, Kenneth N.
Rees, Charles W.
Vögtle, Fritz
Bazin, D.
Bianconi, A.
Clement, R.
Dexpert, H.
Galy, J.
Lagarde, P.
Laggner, P.
Mathey, Y.
Michalowicz, A.
Source :
Synchrotron Radiation in Chemistry & Biology I; 1988, p29-67, 39p
Publication Year :
1988

Abstract

In this short review of recent advances in XANES we have discussed the use of this spectroscopy to probe the geometry of local structure via multiple scattering effects in the real space and and the local partial unoccupied density of states in metals via the band structure approach. Several important aspects of x-ray absorption spectroscopy have not be considered such as the excitonic effects, the many body infrared singularities in free electron metals and the many body final state configurations in solids with high electronic correlation such as the valence fluctuating metals and correlated oxides as CeO2 and the new high Tc oxide superconsuctors. These effects require to go beyond the one-electron aproximation discussed here but give important information on the local electronic structure of materials. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISBNs :
9783540183853
Database :
Supplemental Index
Journal :
Synchrotron Radiation in Chemistry & Biology I
Publication Type :
Book
Accession number :
33243094
Full Text :
https://doi.org/10.1007/BFb0111235