Interlayer deficient micas, stilpnomelane, ganophyllite group and related silicates.

This document is part of Subvolume I5a ‘Phyllosilicates' of Volume 27 ‘Magnetic properties of non-metallic inorganic compounds based on transition elements' of Landolt-Börnstein - Group III ‘Condensed Matter'. It presents interlayer deficient micas, stilpnomelane, the ganophyllite group and related silicates with regard to their crystal structures, lattice parameters, nuclear gamma resonance (NGR) data, electron spin resonance (ESR) data, nuclear magnetic resonance (NMR) data, and infrared and optical data. Mineral names contained in this document: ammonium hydromica, bannisterite, biotite, brammallite, celadonite, eggletonite, ekmanite, ferrostilpnomelane, ganophyllite, glauconite, hydrobiotite, illite, illite/sericite, illite/smectite, kaolinite, kaolinite-illite, lennilenapeite, manganoan zussmanite, mica, mica-montmorillonite, minnesotaite, montmorillonite, mullite, muscovite, paragonite, parsettensite, rectorite, sericite, smectite, stilpnomelane, sturtite, talc, tamaite, vermiculite, wonesite, zussmanite. Substances contained in this document (element systems and chemical formulae): A-Al-Fe-H-Mg-O-Si: A+1.60(Al3.32Mg0.60Fe3+0.06Fe2+0.10)(Si6.86Al1.14)O20(OH)4, A+1.86(Al3.24Mg0.60Fe3+0.06Fe2+0.10)(Si6.80Al1.20)O20(OH)4. A-Al-H-M-O-Si: AM10T16O38(OH)9·6H2O (A = K+, Na+, Ca2+; M = Mn, Fe, Mg, Zn; T = Si, Al). A-Al-H-Mg-Mn-O-Si: A+7.5(Mn,Mg)49(Si64.5Al7.5)O168(OH)50. nH2O (A = K, Na, Ca), A7.5(Mn,Mg)49(Si64.5Al7.5)O168(OH)50·nH2O (A = K+, Na+, Ca2+). Al-Ba-Ca-Fe-H-K-Mg-Mn-Na-O-Si-Zn: (K1.06Na0.66Ca0.28Ba0.06)(Mn7.51Mg0.19Zn0.04Fe0.09Al0.86)(Si10.43Al1.57)O31.56(OH)4·7.05H2O. Al-Ba-Fe-H-K-Mg-Mn-Na-O-Si-Zn: (K5.36Ba0.71Na0.54)(Mg14.63Fe2+7.50Mn13.78Zn6.52Fe3+5.57)(Si62.42Al8.93Fe3+0.65)(O171.29OH44.71)·16.94H2O. Al-Ca-Cr-F-Fe-H-K-Mg-Mn-Na-O-Si-Ti: (Ca0.004Na0.790K0.145)(Mg4.390Fe0.778Mn0.004Cr0.008Ti0.074Al0.620)(Al1.534Si6.466)O20(OH,F)4. Al-Ca-Fe-H-K-Mg-Mn-Na-O-Si: (Ca0.25K0.17Na0.12)(Mn5.73Mg0.05Fe0.01Al0.21)(Si9.15Al0.85)O24(OH)4·3.72H2O, (K,Na,Ca)0.4(Fe,Mg,Mn,Al)6.7Si8O20(OH,O)6.6·2.9H2O, (K,Na,Ca)0.5(Fe,Mg,Mn,Al)6.8Si8O20(OH,O)6.1·2.8H2O, (K,Na,Ca)6(Mg,Fe,Mn)24(Si32.5Al7.5)O96(OH)16·21H2O, (K,Na,Ca)6(Mg,Fe,Mn)24(Si32.5Al7.5O96)(OH)16·21H2O, (K0.64Ca0.44Na0.14)(Fe2+9.17Fe3+4.63Mg3.6Mn2+6)[Si27.3Al4.7O78.32](OH)11.37, Si65.0[4]Al7.0[6]Al1.9Fe3+8.4Fe2+28.9Mn0.7Mg8.1Ca0.7Na0.4K3.3(OH)-37.7H+2.0(H2O)19.1. Al-Ca-Fe-H-K-Mg-Mn-Na-O-Si-Ti: Si62.7[4]Al9.3[6]Al2.2Ti0.2Fe3+30.3Fe2+1.2Mn3.2Mg10.9Ca1.0Na3.5K0.7(OH)-15.2H+3.1(H2O)29.0. Al-Ca-Fe-H-K-Mg-Mn-Na-O-Si-Zn: (Ca0.8Na2.0K3.3)(Mn23.0Fe0.3Zn0.1Mg0.6)(Si32.1Al7.5)O96(OH)16·21H2O, (Na0.82K0.40Ca0.39☐0.39)(Mn6.61Zn0.08Mg0.16Fe0.61Al0.56)(Si10.33Al1.67)[(O28.92(OH)3.08)(OH)4.00·10.66H2O, Ca0.86(K0.82Na0.11)(Mn12.21Fe2+2.92Mg2.85Zn2.09Fe3+0.66)(Si28.53Al3.05)O76(OH)16·12.2H2O. Al-Ca-Fe-H-K-Mg-Mn-O-Si: (K,Ca)0.3(Fe,Mg,Mn,Al)6.7Si8O20(OH,O)5.9·2.2H2O, Si65.5[4]Al6.5[6]Al1.9Fe3+8.9Fe2+28.8Mn1.0Mg7.4Ca0.5K2.3(OH)-37.2H+3.2(H2O)14.5. Al-Ca-Fe-H-K-Mg-Na-O-Si: (K,Ca,Na)(Fe,Mg,Al)12(Si,Al)16(O,OH)54·nH2O. Al-Ca-Fe-H-K-Mg-O-Si: (K0.655Ca0.059)(Si3.597Al0.403)Fe0.628Al0.969Mg0.40O10(OH)2. Al-Ca-Fe-H-Mn-O-Si: (Mn,Al,Fe,Ca)3Si4O10(OH)3·H2O. Al-Ca-H-K-Mn-Na-O-Si:[Cax(K,Na)y](Mn6-zAlz)[Si8Al2+x+y+zSi2-2x-y-z]O24(OH)4·nH2O, [Cax(K,Na)y][6](Mn6-zAlz)[4][Si8Al2+x+y+zSi2-2x-y-z]O24(OH)4·nH2O. Al-Cl-H-K-Mg-Na-O-Si: Na2O-K2O-MgO-Al2O3-SiO2-H2O-HCl. Al-Fe-H-K-Mg-Mn-Na-O-Si-Ti: (Na0.07K0.92)(Mg1.53Mn0.46Fe2+10.85Fe3+0.11Al0.34Ti0.01)(Si16.6Al1.4)O42.2(OH)13.8, Si64.1[4]Al7.9[6]Al1.0Ti0.1Fe3+23.4Fe2+20.0Mn0.4Mg3.1Na3.8K2.4(OH)-23.4H+1.6(H2O)29.8. Al-Fe-H-K-Mg-Mn-O-Si: K(Fe,Mg,Mn)13(Si,Al)18O42(OH)14. Al-Fe-H-K-Mg-Na-O-Si: (K,Na)x+y(Mg,Fe2+)x(Al,Fe3+)2-x☐Si4-y(Al,Fe3+)yO10(OH)2.Al-Fe-H-K-Mg-O-Si: K(Mg,Fe)6(Si,Al)8O20(OH)4·xH2O. Al-Fe-H-K-Mn-O-Si: KAlMn3...5Fe2+10...8Si17O42(OH)14,… [ABSTRACT FROM AUTHOR]