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Syntheses and Properties of Thiophene-inserted [3]Dendralenes with Redox-active 1,3-Dithiol-2-ylidene Units.

Authors :
Hasegawa, Masashi
Fujioka, Atsushi
Kubo, Takashi
Honda, Tomohito
Miyamoto, Hisakazu
Misaki, Yohji
Source :
Chemistry Letters; 4/5/2008, Vol. 37 Issue 4, p45-45, 1p
Publication Year :
2008

Abstract

Novel dendralene type cross-conjugate molecules based on 1,3-dithiol-2-ylidene units with thiophene have been prepared. The conjugation in the oxidized stage is mainly through the thiophene core, while the cross-conjugated nature is observed in the neutral state. The CT complex of 2a with TCNQF<subscript>4</subscript> shows moderated electrical conductivity of 10<superscript>-4</superscript> S cm<superscript>-1</superscript>. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
37
Issue :
4
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
31770153
Full Text :
https://doi.org/10.1246/cl.2008.474