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Control of Stereoselectivity in 4-tert-Butylphenol Hydrogenation over a Carbon-supported Rhodium Catalyst by Carbon Dioxide Solvent.

Authors :
Hiyoshi, Norihito
Mine, Eiichi
Rode, Chandrashekhar V.
Sato, Osamu
Ebina, Takeo
Shirai, Masayuki
Source :
Chemistry Letters; 9/5/2006, Vol. 35 Issue 9, p39-39, 1p
Publication Year :
2006

Abstract

cis-4-tert-Butylcyclohexanol was obtained with a high cis ratio (cis/(cis + trans) = 0.9) in the hydrogenation of 4-tert-butylphenol over a carbon-supported rhodium catalyst along with hydrochloric acid in supercritical carbon dioxide solvent. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
35
Issue :
9
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
22825200
Full Text :
https://doi.org/10.1246/cl.2006.1060