Factors that influence the migration of sorbed pesticides in polyethylene and biodegradable mesoplastics.

Trifluralin, Chlorpyrifos, and Procymidone migration performance from polyethylene (PE) and biodegradable (Mater-Bi: M-B) mulching films was examined. Desorption of pesticides from PE and M-B was studied using soil-plastic microcosms, considering temperature, soil humidity, and mulching film type as experimental variables. Trifluralin and Chlorpyrifos desorption was higher for PE than for M-B under all experimental conditions. In both cases, as the temperature increased from 25 °C to 40 °C, pesticide migration also increased, whereas as the soil humidity raised from 30% to 60%, pesticide desorption decreased. In the case of Procymidone, migration from PE and M-B at 25 °C was similar under both soil moisture conditions. Migration percentages were similar for both mulch films at 40 °C and 30% soil humidity. However, at higher soil moisture (60%), migration from M-B was greater than from PE. A linear relationship was observed between the percentage of migration and the vapor pressure of the pesticides. In all cases, migration increased with higher vapor pressure, indicating a possible migration mechanism in the vapor phase. Pesticide migration increased at high temperatures (40 °C). The effect of soil humidity in reducing pesticide migration was more significant at lower levels (30%). In addition, the mesoplastic sorption of pesticides in soil columns was studied using PE and M-B films. While the recoveries for Trifluralin, Chlorpyrifos, and Procymidone in the PE films were 0.05% ± 0.01%, 0.13% ± 0.03%, and non-detectable, the recoveries for M-B were: 0.49% ± 0.07%, 0.31% ± 0.09%, and 0.17% ± 0.10%, respectively, indicating that M-B was a better adsorbent than PE in all cases. This behavior should be considered in combination with the lower migration percentages observed for this type of mulching film in the microcosm experiments. These results could indicate a potential carrier effect of pesticide on biomesoplastic in the environment. [Display omitted] Trifluralin and Chlorpyrifos migration was higher from PE than Mater-Bi. In the case of Procymidone migration from both surfaces was similar. Soil humidity reduced Trifluralin and Chlorpyrifos migration from Mater-Bi. For each plastic surface migration correlates with pesticide vapor pressure. In soil, Mater-Bi is a better adsorbent than PE for the pesticides under test. [ABSTRACT FROM AUTHOR]