Downstream change of luminescence sensitivity in sedimentary quartz and the rearrangement of optically stimulated luminescence (OSL) components along two large rivers.

Recently, it has been proposed that the luminescence sensitivity of quartz grains, i.e. their luminescence response to unit dose, might be used for sediment fingerprinting. Sensitivity is determined both by the origin of quartz grains and the sedimentary processes they underwent. However, a more detailed understanding of the factors influencing sensitivity is essential in order to expand and specify the applicability of the parameter in sediment sourcing and geomorphological studies alike. In the present research, we examined the spatial changes of sensitivity parameters of coarse grain quartz in modern sediments of the largest rivers of the Carpathian Basin, Central Europe, to determine the role of source areas and transportation distance. Based on the luminescence analysis of 39 samples, quartz extracts with a Carpathian origin (catchment of the Tisza River) have a significantly higher sensitivity, except the LM-OSL medium component, than those originating from the Alpine domain (catchment of the Danube River). No clear relationship could be identified between natural sensitisation and transportation distance. In terms of the Tisza the observed downstream increase of quartz sensitivity is due to high sensitivity quartz grains supplied by its tributaries. In the meantime, a recurring change was observed along the Danube, which can be attributed mostly to local erosional processes. Consequently, tributaries and erosion can overprint the potential downstream sensitisation of quartz grains in large rivers. Meanwhile, in terms of the Danube on sections where a significant downstream increase was detected in LM-OSL fast component sensitivity, LM-OSL medium component sensitivity systematically decreased. Additionally, during laboratory sensitisation, the CW-OSL sensitivity of Danube samples increased considerably, whereas changes were more moderate in the case of Tisza samples. Moreover, in the case of Tisza-related quartz extracts, the 110 °C TL sensitivity and the LM-OSL fast and medium components showed a strong correlation, indicating the stability of luminescence processes (trapping and recombination). Whereas, in the case of the Danube both LM-OSL components show a weak correlation with the 110 °C TL intensity. All these indicate that Alpine-origin quartz grains are more susceptible to the rearrangement of electron traps and/or recombination centres, which can also be an indicator of sediment sources in Quaternary studies in the region. • In most cases, the Tisza has higher average sensitivity values than the Danube. • Tributaries are important in the change of quartz sensitivity along the Tisza. • Alpine quartz is more susceptible to the rearrangement of recombination centres. [ABSTRACT FROM AUTHOR]