Experimental evaluation of electrochemically mediated amine regeneration integrated with amine thermal swing for CO2 capture at optimized desorption temperatures.

In the present study, the integration of electrochemically mediated amine regeneration (EMAR) with amine thermal swing process is investigated as a novel method for CO 2 capture, utilizing experimental practical data. The aim is to increase the absorption-desorption temperature difference in order to improve the energy efficiency of the capture process and hamper the amine degradation issue at high desorption temperatures. A comprehensive experimental procedure is presented, and an experimental process setup is designed and constructed. As the main novelty of the study a special heating-cooling subsystem is incorporated with the base EMAR process in order to devise a combined electrochemical-thermal system. The performance of the system is evaluated at sequential incremental desorption temperatures while the absorption temperature is kept constant. Relevant data, including the desorbed CO 2 flow, absorbed CO 2 flow, stream points temperature, and cell voltage are collected. Based on the data collected, two performance parameters are calculated, including normalized carbon separation work, and CO 2 desorption density. Based on these performance parameters the system's capability is assessed, and the optimal desorption temperature is ultimately selected. The presented electrochemical-thermal CO 2 separation system, operating with a chloride salt system, demonstrates its best energetics performance at a desorption temperature of 44 °C, resulting in a normalized capture work of 95.2 kJ/molCO 2. Under these optimal conditions, the cell's average voltage is measured to be 0.37 V, and the CO 2 desorption density is determined to be 0.71 l.min⁻¹.m⁻². • Novel integration of EMAR and thermal swing for energy-efficient CO 2 capture is proposed. • Unique heating-cooling subsystem enhances the electrochemical-thermal system. • Performance evaluated by calculating capture work and CO 2 desorption density. • Optimal desorption at 44°C, achieving work of 95.2 kJ/molCO 2 with 0.37 V voltage. [ABSTRACT FROM AUTHOR]