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π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO2 to Ketenyl Transformation.

Authors :
Lachguar, Abdelhak
Del Rosal, Iker
Maron, Laurent
Jeanneau, Erwann
Veyre, Laurent
Thieuleux, Chloé
Camp, Clément
Source :
Journal of the American Chemical Society; 7/10/2024, Vol. 146 Issue 27, p18306-18319, 14p
Publication Year :
2024

Details

Language :
English
ISSN :
00027863
Volume :
146
Issue :
27
Database :
Supplemental Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
178847549
Full Text :
https://doi.org/10.1021/jacs.4c02172