Efficient Nimesulide degradation via chlorination and sun-simulated radiation: Kinetic insights, reactive species formation, and application to real wastewater.

Hypochlorite mediated oxidation had been established as an efficient process for degrading organic pollutants in water. In this research work, it was evaluated the synergistic potential of solar light irradiation combined with hypochlorite on a emerging contaminant model such as Nimesulide (NIM), a nonsteroidal anti-inflammatory drug. These experiments shown that at pH 3.0, where only hypochlorous acid (HOCl) prevails, the degradation constant of NIM exhibited an increase from 2.50 × 10⁻⁴ s⁻¹ (under dark conditions) to 1.53 × 10⁻³ s⁻¹ (sun-simulated radiation), signifying an approximately six-fold acceleration in degradation. Moreover, under approximately neutral pH value (7.5) wherein both HOCl and hypochlorite ion (ClO⁻) coexist, the enhancement observed was approximately twofold, in particular a mineralization up to 32 % was observed. This investigation also included quenching experiments conducted at varying pH levels, shedding light on the role of specific reactive species and their contributions to the degradation mechanism. The impact of synergistic effect between solar-simulated irradiation and hypochlorite systems on NIM degradation showcases a remarkable kinetic enhancement, particularly evident at lower pH values. The degradation byproducts have been identified via high resolution HPLC-MS and the main ion formed during the reaction have been monitored by IC-MS. Experiments in real sewage treatment plant waters using sun radiation revealed the promising potential and efficiency of this alternative method, despite a comparatively lower degradation rates when compared with UV lamp application. This approach offers a sustainable and economically advantageous solution for wastewater treatment. [Display omitted] • Sun-simulated radiation was used to activate free active chlorine in water. • Photogeneration of reactive oxygen and chlorine species was determined using competition kinetic approach. • Efficient degradation of Nimesulide was provided in real sewage treatment plant water. • Sun-simulated irradiation modifies the chlorinated products formation. [ABSTRACT FROM AUTHOR]