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Insight into the large electro-strain in bismuth sodium titanate-based relaxor ferroelectrics: From fundamentals to regulation methods.
- Source :
- Journal of Materials Science & Technology; Jul2023, Vol. 150, p27-48, 22p
- Publication Year :
- 2023
-
Abstract
- • Strain origin. Firstly, to comprehend the intrinsic strain contribution, the strain origin is introduced from macroscopic and microscopic views, respectively. • Phase structure. Secondly, considering the origin of giant electro-strain in BNT-based materials (i.e., relaxor-ferroelectric transition), the phase structure of typical BNT-based materials is summarized from two aspects (i.e., crystal structure and relaxor structure). • Strain regulation and fundamental regulation mechanism. Then, mainstream strain regulation methods (e.g., chemical substitution, texturing), and the intrinsic strain regulation mechanism (how do dopants work) are introduced. • Perspectives. Finally, our perspectives on the strain regulation and industrial process of BNT-based materials (e.g., facing obstacles, such as nonlinear hysteresis) are given out. Due to the demand for environmental protection, developing eco-friendly piezoelectric applications/materials is an inevitable trend. The market share of lead-free materials is growing steadily every year. Among typical lead-free systems, Bi 0.5 Na 0.5 TiO 3 (BNT) has attracted wide attention due to its superior strain property (e.g., dynamic piezoelectric coefficient d 33 * of most modified-BNT ceramics exceeds 600 pm/V, which is higher than commercial soft PZT ceramics PIC151). The excellent strain performance in BNT-based materials is thought to arise from the relaxor-ferroelectric transition, and currently, the mainstream strain regulation method is chemical modifying. So far, amounts of effective dopants have been investigated, while the intrinsic strain regulation mechanism is still ambiguous (e.g., how do dopants work ?). Therefore, we review the intrinsic strain regulation mechanism, and strain origination and regulation methods are also investigated to comprehend the regulation mechanism. Significantly, the strain origination and regulation mechanism are investigated from different dimensions (e.g., macro perspective and micro perspective), which is vacant in previous reports. From the macro view, the particular tailored relaxor-ferroelectric crossover is the critical key for the giant electro-strain, while from the micro view, the electro-strain is dominated by the cracked ferroelectric order and relaxor-ferroelectric transition, resulting from the broken Bi-O bonds due to the local field effect. Exploring the strain origination and regulation mechanism of BNT-based ceramics is of great importance to exclude the blind researching mode and rationally design the experimental scheme. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10050302
- Volume :
- 150
- Database :
- Supplemental Index
- Journal :
- Journal of Materials Science & Technology
- Publication Type :
- Periodical
- Accession number :
- 163586596
- Full Text :
- https://doi.org/10.1016/j.jmst.2022.12.016