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Mechanochemical Acetylene Hydrogenation on Fragments of Ni-based Alloys Containing Oxophilic Metal Elements.

Authors :
Tomoaki Takayama
Takayuki Komatsu
Source :
Chemistry Letters; Feb2022, Vol. 51 Issue 2, p111-113, 3p
Publication Year :
2022

Abstract

Mechanochemical hydrogenation of acetylene on fragments of Ni-based alloys was investigated using planetary ball milling. Intermetallic compounds (IMCs) and solid solutions were employed as alloys. Among the alloys, NiAl and NiGa IMCs as well as Ni<subscript>0.5</subscript>Fe<subscript>0.5</subscript> solid solution retained their crystal structures after the pulverization. The pulverization exposed fresh surfaces on which ethylene is adsorbed weakly compared to the monometallic Ni surface. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
51
Issue :
2
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
154875025
Full Text :
https://doi.org/10.1246/cl.210600