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VOCs photocatalytic abatement using nanostructured titania-silica catalysts.

Authors :
Iqbal, Javed
Ali, Zulfiqar
Majeed, Khaliq
Sheikh, Rizwan
Amjad, Um-e-salma
Hussain, Murid
Shehzad, Nasir
Russo, Nunzio
Akhter, Parveen
Yang, Wenshu
Source :
Journal of Environmental Chemical Engineering; Aug2017, Vol. 5 Issue 4, p3100-3107, 8p
Publication Year :
2017

Abstract

In this work, different quantities of TiO 2 incorporated into TiO 2 -KIT6 nanostructured catalysts were considered to improve the photocatalytic abatement of volatile organic compounds (VOCs; ethylene, propylene) at ambient temperature. The best optimized activity and stability of the catalysts toward(s) ethylene and propylene degradation has been shown for 30 wt% TiO 2 , while the worst conversion has been observed for a 90 wt% TiO 2 loading. This was likely due to the dispersion and stabilization of the anatase TiO 2 with 30 wt% on KIT-6, which in turn allowed more VOCs adsorption and better light penetration than 90% TiO 2 /KIT-6 in which it showed a bulk phase and large agglomerates with light penetration limitations. VOC abatement has been found to be not only influenced directly by the dispersed TiO 2 contents but also by the calcination temperatures, and 500 °C has been found to be the best calcination condition to achieve the highest propylene conversion. The optimized nanostructured photocatalyst developed for ethylene and propylene, could also be promising candidate for other VOCs and different applications. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
22133437
Volume :
5
Issue :
4
Database :
Supplemental Index
Journal :
Journal of Environmental Chemical Engineering
Publication Type :
Academic Journal
Accession number :
124936888
Full Text :
https://doi.org/10.1016/j.jece.2017.06.014