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Conducting π-Conjugated Bis(iminothiolato)nickel Nanosheet.
- Source :
- Chemistry Letters; Aug2017, Vol. 46 Issue 8, p1081-1084, 4p
- Publication Year :
- 2017
-
Abstract
- A π-conjugated coordination nanosheet (CONASH) comprising bis(iminothiolato)nickel moieties, NiIT, was synthesized by a reaction of Ni<superscript>2+</superscript> with 1,3,5-triaminobenzene-2,4,6-trithiol (L) in the presence of ferrocenium ions. A bulk material, bulk-NiIT, prepared in a homogeneous solution was characterized by XPS, IR, and SEM. A liquidliquid interfacial reaction using bis(2,4-pentanedionato)nickel(II) in CH<subscript>2</subscript>Cl<subscript>2</subscript> and L in H<subscript>2</subscript>O afforded a semiconducting nanosheet, nano-NiIT. AFM, SEM, and TEM observation of nano-NiIT revealed the uniform and flat nature of a stacked layer nanosheet. Selected-area electron diffraction (SAED) analysis indicated the formation of a twodimensional hexagonal crystal structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03667022
- Volume :
- 46
- Issue :
- 8
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Academic Journal
- Accession number :
- 124007653
- Full Text :
- https://doi.org/10.1246/cl.170382