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Self-sustained catalytic combustion of carbon monoxide ignited by dielectric barrier discharge.
- Source :
- Proceedings of the Combustion Institute; 2017, Vol. 36 Issue 3, p4193-4200, 8p
- Publication Year :
- 2017
-
Abstract
- This paper presents the results of a study of self-sustained catalytic combustion of CO ignited by dielectric barrier discharge (DBD) using Ce 0.5 Zr 0.5 O y /TiO 2 (CeZr/Ti), CuZr 0.25 O y /TiO 2 (CuZr/Ti), and CuCe 0.75 Zr 0.25 O y /TiO 2 (CuCeZr/Ti) catalysts. DBD excites and dissociates some of the reactant molecules in the gas phase. These are more easily adsorbed on the catalyst surface than are ground-state species, therefore induction begins at a lower background temperature than in thermal catalysis. CO is adsorbed on copper sites, therefore CeZr/Ti is inactive in CO ignition, but CuZr/Ti and CuCeZr/Ti achieve DBD ignition at 34 and 44 s, respectively, at a specific energy density (SED) of 1500 J/L. CO catalytic ignition by DBD involves two steps. The induction process is dominated by plasma catalysis. At the same SEDs, induction with CuCeZr/Ti begins earlier than those with CuZr/Ti, in good agreement with the reducibilities and oxygen-transfer properties of these catalysts. The ignition process is governed by thermal catalysis because the enhancement of external diffusion induced by increasing the temperature improves the reaction rate. CuZr/Ti provided more CO adsorption sites than did CuCeZr/Ti, contributing to shortening of the ignition delay. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15407489
- Volume :
- 36
- Issue :
- 3
- Database :
- Supplemental Index
- Journal :
- Proceedings of the Combustion Institute
- Publication Type :
- Academic Journal
- Accession number :
- 121156582
- Full Text :
- https://doi.org/10.1016/j.proci.2016.06.181