Back to Search Start Over

Synthesis of Dibenzosiloles via Platinum-catalyzed Intramolecular Dehydrogenative Cyclization of 2-(Dialkylsilyl)biaryls.

Authors :
Miki Murata
Miho Takizawa
Haruto Sasaki
Yoshihito Kohari
Hirotoshi Sakagami
Takeshi Namikoshi
Shinji Watanabe
Source :
Chemistry Letters; 8/5/2016, Vol. 45 Issue 8, p857-859, 3p, 3 Diagrams, 2 Charts
Publication Year :
2016

Abstract

The intramolecular dehydrogenative cyclization of 2-(dialkylsilyl) biaryls proceeded in the presence of a catalytic amount of platinum(II) chloride and potassium tris(3,5-dimethyl-1- pyrazolyl)borohydride to give good yields of the corresponding dibenzosilole derivatives. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
45
Issue :
8
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
120772972
Full Text :
https://doi.org/10.1246/cl.160415