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Synthesis and Photoproperties of Edge-functionalized Zeolite-templated Carbon with Bromine or Carbazole Groups.

Authors :
Haruko Goto
Tomoyuki Tajima
Kazumasa Kobayashi
Yutaka Takaguchi
Khanin Nueangnoraj
Hirotomo Nishihara
Source :
Chemistry Letters; 6/5/2016, Vol. 45 Issue 6, p601-603, 3p
Publication Year :
2016

Abstract

We succeeded in synthesizing edge-brominated zeolitetemplated carbon (ZTC-Br) as the key intermediate of edgefunctionalization of ZTC via an electrophilic aromatic substitution reaction using dibromoisocyanuric acid. ZTC-Br was easily converted into carbazole-modified ZTC (ZTC-Cz) using SuzukiMiyaura coupling. Interestingly, solvent-dependent changes of the fluorescence intensity of ZTC-Cz owing to its swellingshrinking behavior were observed. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
45
Issue :
6
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
120710668
Full Text :
https://doi.org/10.1246/cl.160123