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Chemical Reactivities of LaScO3-based Perovskite Oxides and Platinum.

Authors :
Katsuhiro Nomura
Hiroyuki Kageyama
Kentaro Ohmi
Mitsuharu Fujita
Tetsuya Ueda
Source :
Chemistry Letters; 10/5/2013, Vol. 42 Issue 10, p1268-1270, 3p
Publication Year :
2013

Abstract

We investigated the chemical reactivities of (La<subscript>0.7</subscript>Sr<subscript>0.2</subscript>-Ba<subscript>0.1</subscript>)ScO<subscript>3-δ</subscript> (LSBS) and LaScO<subscript>3</subscript> powders and Pt foil as functions of reaction temperature, T, oxygen partial pressure, P(O<subscript>2</subscript>), and reaction time, t. The LSBS powder showed a maximal Pt content of ca. 33 mg (ca. 3 wt%) under the conditions T = 1573 K, P(O<subscript>2</subscript>) = 0.21 atm (in air), and t = 10 h. Subsequent heat treatment at 1773K in air for 10 h resulted in the deposition of Pt fine particles (1.7 mg) on the LSBS powder and a weight gain of the Pt foil (4.3 mg). [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
42
Issue :
10
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
120710435
Full Text :
https://doi.org/10.1246/cl.130550