High efficiency, Pt-free photoelectrochemical cells for solar hydrogen generation based on “giant” quantum dots.

Quantum dot (QD) sensitized TiO 2 is considered as a highly promising photoanode material for photoelectrochemical (PEC) solar hydrogen production. However, due to its limited stability, the photoanode suffers from degradation of its long-term PEC performance. Here, we report the design and characterization of a high-efficiency and long-term stable Pt-free PEC cell. The photoanode is composed of a mesoporous TiO 2 nanoparticle film sensitized with “giant” core@shell QDs for PEC solar hydrogen generation. The thick shell enhances light absorption in the visible range, increases the stability of the QDs and does not inhibit charge separation, injection and transport, needed for proper operation of the device. We prepared thin films of Cu 2 S nanoflakes through a simple and reproducible procedure, and used them as counter-electrodes replacing the standard Pt film, resulting in equivalent performances of the PEC cell. We obtained an unprecedented photocurrent density (~10 mA/cm 2 ) for “giant” QDs based PEC devices (and corresponding H 2 generation) and a very promising stability, indicating that the proposed cell architecture is a good candidate for long-term stable QD-based PEC solar hydrogen generation. [ABSTRACT FROM AUTHOR]