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An efficient aldol-type reaction of ethyl diazoacetate with aldehydes promoted by MgI2 etherate.
- Source :
- Journal of Chemical Research; Nov2014, Vol. 38 Issue 11, p690-691, 2p
- Publication Year :
- 2014
-
Abstract
- The first example of the preparation of α-diazo-β-hydroxy esters by the aldol-type condensation of aldehydes with ethyl diazoacetate using Et<subscript>3</subscript>N as base in the presence of magnesium iodide etherate [MgI<subscript>2</subscript>.(Et<subscript>2</subscript>O)<subscript>n</subscript>] has been achieved in good to excellent yields at room temperature in CH<subscript>2</subscript>Cl<subscript>2</subscript> in 15-30 min. [ABSTRACT FROM AUTHOR]
- Subjects :
- HYDROXY esters
ALDEHYDES
ORGANIC compounds
OXO compounds
FORMYL radicals
MAGNESIUM
Subjects
Details
- Language :
- English
- ISSN :
- 17475198
- Volume :
- 38
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Journal of Chemical Research
- Publication Type :
- Academic Journal
- Accession number :
- 99595809
- Full Text :
- https://doi.org/10.3184/174751914X14145853961149