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Uniaxial Movements of a Metal-Cyanide Framework Switched by Weak Interactions through Dehydration and Rehydration.
- Source :
- Chemistry - A European Journal; Jul2014, Vol. 20 Issue 27, p8269-8273, 5p
- Publication Year :
- 2014
-
Abstract
- A metal-cyanide framework undergoes a dehydration-rehydration triggered reversible single-crystal-to-single-crystal transformation. The resulting accordion-like contraction-expansion corresponds to a size change along the c axis as much as 24 %. This anisotropic response arises from the cooperativity among the water molecules, K ions, and CN groups between the unique two-dimensional bimetallic layers through weak interactions of hydrogen bonds and electrostatic (ionic) interactions. The key role of the water molecules in the dehydration-rehydration process is revealed by solid-state <superscript>1</superscript>H NMR spectroscopy and dielectric measurements. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 20
- Issue :
- 27
- Database :
- Complementary Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 96775315
- Full Text :
- https://doi.org/10.1002/chem.201402892