Chemical composition and mass closure of ambient coarse particles at traffic and urban-background sites in Thessaloniki, Greece.

Concentrations and chemical composition of the coarse particle fraction (PM) were investigated at two urban sites in the city of Thessaloniki, Greece, through concurrent sampling of PM and PM during the warm and the cold months of the year. PM levels at the urban-traffic site (UT) were among the highest found in literature worldwide exhibiting higher values in the cold period. PM levels at the urban-background site (UB) were significantly lower exhibiting a reverse seasonal trend. Concentration levels of minerals and most trace metals were also higher at the UT site suggesting a stronger impact from traffic-related sources (road dust resuspension, brake and tire abrasion, road wear). According to the chemical mass closure obtained, minerals (oxides of Si, Al, Ca, Mg, Fe, Ti, and K) dominated the PM profile, regardless of the site and the period, with organic matter and secondary inorganic aerosols (mainly nitrate) also contributing considerably to the PM mass, particularly in the warm period. The influence of wind speed to dilution and/or resuspension of coarse particles was investigated. The source of origin of coarse particles was also investigated using surface wind data and atmospheric back-trajectory modeling. Finally, the contribution of resuspension to PM levels was estimated for air quality management perspectives. [ABSTRACT FROM AUTHOR]