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How to Modulate Catalytic Properties in Nanosystems: The Case of Iron-Ruthenium Nanoparticles.
- Source :
- ChemCatChem; Jun2014, Vol. 6 Issue 6, p1714-1720, 7p
- Publication Year :
- 2014
-
Abstract
- Ultrasmall FeRu bimetallic nanoparticles were prepared by co-decomposition of two organometallic precursors, {Fe[N(Si(CH<subscript>3</subscript>)<subscript>3</subscript>)<subscript>2</subscript>]<subscript>2</subscript>}<subscript>2</subscript> and (η<superscript>4</superscript>-1,5-cyclooctadiene)(η<superscript>6</superscript>-1,3,5-cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150 °C in mesitylene. A series of FeRu nanoparticles of sizes of approximately 1.8 nm and incorporating different ratios of iron to ruthenium were synthesized by varying the quantity of the ruthenium complex introduced (Fe/Ru=1:1, 1:0.5, 1:0.2, and 1:0.1). FeRu nanoparticles were characterized by TEM, high-resolution TEM, and wide-angle X-ray scattering analyses. Their surface was studied by hydride titration and IR spectroscopy after CO adsorption and their magnetic properties were analyzed by using a superconducting quantum interference device (SQUID). The FeRu nanoparticles were used as catalysts in the hydrogenation of styrene and 2-butanone. The results indicate that the selectivity of the nanoparticle catalysts can be modulated according to their composition and therefore represent a case study on fine-tuning the reactivity of nanocatalysts and adjusting their selectivity in a given reaction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18673880
- Volume :
- 6
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- ChemCatChem
- Publication Type :
- Academic Journal
- Accession number :
- 96362778
- Full Text :
- https://doi.org/10.1002/cctc.201300907