Global emissions of HFC-143a (CH3CF3) and HFC-32 (CH2F2) from in situ and air archive atmospheric observations.

High frequency, in situ observations from the Advanced Global Atmospheric Gases Experiment (AGAGE), for the period 2003 to 2012, combined with archive flask measurements dating back to 1977, have been used to capture the rapid growth of HFC-143a (CH₃CF₃) and HFC-32 (CH₂F₂) mole fractions and emissions into the atmosphere. Here we report the first in situ global measurements of these two gases. HFC-143a and HFC-32 are the third and sixth most abundant HFCs respectively and they currently make an appreciable contribution to the HFCs in terms of atmospheric radiative forcing (1.7 and 0.7mWm² in 2012, respectively). In 2012 the global average mole fraction of HFC-143a was 13.4±0.3 ppt (1-sigma) in the lower troposphere and its growth rate was 1.4±0.04 pptyr^-1; HFC-32 had a global mean mole fraction of 6.2±0.2 ppt and a growth rate of 1.1±0.04 pptyr^-1 in 2012. The extensive observations presented in this work have been combined with an atmospheric transport model to simulate global atmospheric abundances and derive global emission estimates. It is estimated that 23±3Ggyr^-1 of HFC-143a and 21±11Ggyr^-1 of HFC-32 were emitted globally in 2012, and the emission rates are estimated to be increasing 7±5%yr-1 for HFC-143a and 14±11%yr^-1 for HFC-32. [ABSTRACT FROM AUTHOR]