Back to Search
Start Over
Direct structural and spectroscopic investigation of ultrathin films of tetragonal CuO: Six-fold coordinated copper.
- Source :
- Europhysics Letters; Jan2014, Vol. 105, p17003-17007, 5p
- Publication Year :
- 2014
-
Abstract
- Unlike other 3d transition metal monoxides (MnO, FeO, CoO, and NiO), CuO is found in a low-symmetry distorted monoclinic structure rather than the rocksalt structure. We report here of the growth of ultrathin CuO films on SrTiO<subscript>3</subscript> substrates; scanning transmission electron microscopy was used to show the stabilization of a tetragonal rocksalt structure with an elongated c-axis such that and the Cu-O-Cu bond angle , pointing to metastable six-fold coordinated Cu. X-ray absorption spectroscopy demonstrates that the hole at the Cu site for the CuO is localized in orbital unlike the well-studied monoclinic CuO phase. The experimental confirmation of the tetragonal structure of CuO opens up new avenues to explore electronic and magnetic properties of six-fold coordinated Cu. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02955075
- Volume :
- 105
- Database :
- Complementary Index
- Journal :
- Europhysics Letters
- Publication Type :
- Academic Journal
- Accession number :
- 94382927
- Full Text :
- https://doi.org/10.1209/0295-5075/105/17003