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Pd-Carbene Migratory Insertion: Application to the Synthesis of Trifluoromethylated Alkenes and Dienes.
- Source :
- Chemistry - A European Journal; Jan2014, Vol. 20 Issue 4, p961-965, 5p
- Publication Year :
- 2014
-
Abstract
- Pd-catalyzed cross-coupling of halides with CF<subscript>3</subscript>-substituted diazo compounds or N-tosylhydrazones has been explored for the synthesis of CF<subscript>3</subscript>-substituted alkenes and 1,3-butadienes. Pd-carbene migratory insertion plays the key role in these transformations. [ABSTRACT FROM AUTHOR]
- Subjects :
- HALIDES
CARBENES
TRIFLUOROMETHYL compounds
ALKENES
DIOLEFINS
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 20
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 93662848
- Full Text :
- https://doi.org/10.1002/chem.201304143