First air-sea gas exchange laboratory study at hurricane wind speeds.

In a pilot study conducted in October and November 2011, air-sea gas transfer velocities of the two sparingly soluble trace gases hexafluorobenzene and 1,4- difluorobenzene were measured in the unique High-Speed Wind-Wave Tank at Kyoto University, Japan. This air-sea interaction facility is capable of producing hurricane strength wind speeds of up to u10 = 67ms^-1. This constitutes the first lab study of gas transfer at such high wind speeds. The measured transfer velocities k₆₀₀ spanned two orders of magnitude, lying between 11 cmh^-1 and 1180 cmh^-1 with the latter being the highest ever measured wind induced gas transfer velocity. The measured gas transfer velocities are in agreement with the only available dataset at hurricane wind speeds (McNeil and D'Asaro, 2007). The disproportionately large increase of the transfer velocities found at highest wind speeds indicates a new regime of air-sea gas transfer, which is characterized by strong wave breaking, enhanced turbulence and bubble cloud entrainment. It was found that tracers spanning a wide range of solubilities and diffu sivities are needed to separate the effects of enhanced surface area and turbulence due to breaking waves from the effects of bubble and spray mediated gas transfer. [ABSTRACT FROM AUTHOR]