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Selective Methylation of Amines with Carbon Dioxide and H2.
- Source :
- Angewandte Chemie; Nov2013, Vol. 125 Issue 46, p12378-12382, 5p
- Publication Year :
- 2013
-
Abstract
- The authors focus on the methylation of amines with carbon dioxide and hydrogen molecule (H<subscript>2</subscript>). They mention that two catalysts formed from ruthenium acetylacetonate [Ru(acac)<subscript>3</subscript>] and 1,1,1-tris(diphenylphosphinomethyl) ethane, enabled the conversion of carbon dioxide and carboxylic acid derivatives into N,N-dimethylaniline and N-methylaniline. They mention that methylation reaction with formamide and methanol formed intermediates, which then reduced to a methylated product.
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 125
- Issue :
- 46
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 91899272
- Full Text :
- https://doi.org/10.1002/ange.201306850