Back to Search
Start Over
Perturbation facilitated two-color four-wave-mixing spectroscopy of C3.
- Source :
- Journal of Chemical Physics; Oct2013, Vol. 139 Issue 15, p154203, 8p, 2 Diagrams, 3 Charts, 3 Graphs
- Publication Year :
- 2013
-
Abstract
- Perturbation-facilitated two-color resonant four-wave-mixing spectroscopy is realized to access the (dark) triplet manifold of the C3 molecule from the singlet X<superscript>1</superscript>Σ<subscript>g</subscript><superscript>+</superscript> ground state. The inherent nonlinear signal dependence and coherence of the technique result in a favorable detection of the excited triplet states of interest. The observation of a newly found 3Δu electronic state is achieved by a two-step excitation via 'gate-way' levels (i.e., singlet-triplet mixed levels). Additionally, by fixing the probe laser on a transition exhibiting mainly triplet-triplet character and scanning the pump laser, we demonstrate an effective spin-filtering in a four-wave mixing measurement where only transitions to the perturber <superscript>3</superscript>Σ<subscript>u</subscript><superscript>-</superscript> state appear exclusively in an otherwise congested spectral range of the Comet band. Ab initio calculations of excited triplet states complement our analysis with the electronic assignment of the observed resonances. [ABSTRACT FROM AUTHOR]
- Subjects :
- PERTURBATION theory
APPROXIMATION theory
SPECTRUM analysis
WAVES (Physics)
MOLECULES
Subjects
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 139
- Issue :
- 15
- Database :
- Complementary Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 91552528
- Full Text :
- https://doi.org/10.1063/1.4825198