1-Acyloxygermatranes.

Authors :: Baryshok, V. P.
Thuy Zang, L. N.
Voronkov, M. G.
Source :: Russian Journal of General Chemistry; Aug2013, Vol. 83 Issue 8, p1501-1502, 2p, 2 Charts
Publication Year :: 2013
Abstract: A one-step method for the synthesis of 1-acyloxygermatranes RC(O)OGe(OCH <subscript>2</subscript>CH <subscript>2</subscript>) <subscript>3</subscript>N in the reaction of germanium dioxide with triethanolamine and a carboxylic acid was developed. 1-Acyloxygermatranes, including those containing biologically active acyloxy groups (R = 2-MeC <subscript>6</subscript>H <subscript>4</subscript>CH <subscript>2</subscript>OCH <subscript>2</subscript>, C <subscript>6</subscript>H <subscript>5</subscript>, 2-HOC <subscript>6</subscript>H <subscript>4</subscript>), were obtained with a 82–96.5% yield. [ABSTRACT FROM AUTHOR]