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Direct Oxidative Allylic and Vinylic Amination of Alkenes through Selenium Catalysis.
- Source :
- Angewandte Chemie International Edition; Aug2013, Vol. 52 Issue 34, p8952-8956, 5p
- Publication Year :
- 2013
-
Abstract
- Bringing “N” into the game: The direct chemoselective nitrogenation of unactivated alkenes can be achieved through oxidative selenium catalysis (see scheme). This method provides a broad variety of allylic imides in yields of up to 89 % using N‐fluorobenzenesulfonimide (NFSI) as the terminal oxidant and nitrogen source. Furthermore, an unprecedented selenium‐catalyzed vinylic C(sp2)–H nitrogenation was discovered. [ABSTRACT FROM AUTHOR]
- Subjects :
- SELENIUM
CATALYSIS
AMINATION
ALKENES
ALLYLIC amination
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 52
- Issue :
- 34
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 89703904
- Full Text :
- https://doi.org/10.1002/anie.201303662