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Mn(OAc)3-Mediated Selective Free Radical Phosphonylation of Pyridinones and Pyrimidinones.

Authors :
Sun, Wang-Bin
Ji, Yun-Fei
Pan, Xiang-Qiang
Zhou, Shao-Fang
Zou, Jian-Ping
Wei Zhang
Asekun, Olayinkataiwo
Source :
Synthesis; 2013, Vol. 45 Issue 11, p1529-1533, 5p
Publication Year :
2013

Abstract

The phosphonyl radical generated from the reaction of dimethyl phosphite with manganese(III) acetate adds selectively to the 3-position of pyridin-2-ones or the 5-position of pyrimidin-4-ones to afford phosphonylated products in good yields. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00397881
Volume :
45
Issue :
11
Database :
Complementary Index
Journal :
Synthesis
Publication Type :
Academic Journal
Accession number :
87759096
Full Text :
https://doi.org/10.1055/s-0033-1338423