Exchange bias effect in NiO/NiFe2O4 nanocomposites.

Authors :: Gong, W. J.
Liu, W.
Li, D.
Guo, S.
Liu, X. H.
Feng, J. N.
Li, B.
Zhao, X. G.
Zhang, Z. D.
Source :: Journal of Applied Physics; Apr2011, Vol. 109 Issue 7, p07D711-07D711-3, 1p
Publication Year :: 2011
Abstract: A series of (100-x)NiO/(x)NiFe2O4 nanocomposites (x = 0, 2.5, 5, 8.3, 12.5, 25) synthesized by a chemical coprecipitation method have been investigated. The exchange bias field HE of the nanocomposites reaches a maximum at x = 2.5, and then decreases with increasing x. The decrease of HE is attributed to the formation of isolated ferrimagnetic NiFe2O4 clusters, which is confirmed by observation with the use of high resolution transmission electron microscopy. The temperature dependence of HE and the coercivity HC for pure NiO is different from those with other samples, which is due to the exchange coupling between the uncompensated antiferromagnetic core and disordered surface shell of NiO nanoparticles. [ABSTRACT FROM AUTHOR]