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Highly Diastereoselective Multicomponent Cascade Reactions: Efficient Synthesis of Functionalized 1-Indanols.
- Source :
- Angewandte Chemie International Edition; Jan2013, Vol. 52 Issue 5, p1539-1542, 4p
- Publication Year :
- 2013
-
Abstract
- Trapped: A Michael‐aldol‐type cascade reaction including the trapping of an oxonium ylide through a delayed proton shift leads to the formation of multiple stereocenters in a mild one‐pot synthesis. Enantiomerically pure indanol derivatives with four stereocenters and a stereogenic quaternary carbon center were easily obtained through this method in moderate to good yields. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 52
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 85029411
- Full Text :
- https://doi.org/10.1002/anie.201208391