Magnetism and Pressure-Induced Superconductivity of Checkerboard-Type Charge-Ordered Molecular Conductor Β-(meso-DMBEDT-TTF)2X (X = PF6 and AsF6).

The metallic state of the molecular conductor Β-(meso-DMBEDT-TTF)₂X (DMBEDT-TTF = 2-(5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro- 5,6-dimethyl-1,3-dithiolo[4,5-b][1,4]dithiin, X = PF₆, AsF₆) is transformed into the checkerboard-type charge-ordered state at around 75-80 K with accompanying metalinsulator (MI) transition on the anisotropic triangular lattice. With lowering temperatures, the magnetic susceptibility decreases gradually and reveals a sudden drop at the MI transition. By applying pressure, the charge-ordered state is suppressed and superconductivity appears in Β-(meso-DMBEDT-TTF)2AsF6 as well as in the reported Β-(meso-DMBEDT-TTF)2PF6. The charge-ordered spin-gapped state and the pressure-induced superconducting state are discussed through the paired-electron crystal (PEC) model, where the spin-bonded electron pairs stay and become mobile in the crystal, namely the valence-bond solid (VBS) and the resonant valence bonded (RVB) state in the quarter-filled band structure. [ABSTRACT FROM AUTHOR]