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A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes.
- Source :
- Chemical Communications; 5/21/2009, Issue 19, p2700-2702, 3p
- Publication Year :
- 2009
-
Abstract
- A new mononuclear low-spin nickel(II) dithiolato complex, [NiL<subscript>2</subscript>] (1), reacts with copper iodide to form the heterooctanuclear cluster [{Ni(L)<subscript>2</subscript>}<subscript>2</subscript>(CuI)<subscript>6</subscript>] (2) with four trigonal-planar CuI<subscript>2</subscript>S and two tetrahedral CuI<subscript>2</subscript>S<subscript>2</subscript> sites; anagostic interactions between the nickel(II) ions and aromatic protons have been demonstrated by variable-temperature NMR studies to pertain in solution. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Issue :
- 19
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 78098704
- Full Text :
- https://doi.org/10.1039/b900423h