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Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2.
- Source :
- Chemical Communications; 4/7/2009, Issue 13, p1691-1693, 3p
- Publication Year :
- 2009
-
Abstract
- The 2c-2e<superscript>-</superscript> P-P bonded dimers [(CH)<subscript>2</subscript>(NR)<subscript>2</subscript>P]<subscript>2</subscript> dissociate in solution to give the persistent new 7p radicals [(CH)<subscript>2</subscript>(NR)<subscript>2</subscript>P]·, which are isoelectronic with the well known S/N thiazolyl radicals. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 78044234
- Full Text :
- https://doi.org/10.1039/b821241d